As with all questions having to do with tax law, please consult a legal, tax, or accounting professional for definitive answers to your specific question(s).
No. If you provide professional services for free to a qualifying nonprofit organization, you cannot claim a tax deduction for the value of your time or services on your income taxes, according to IRS Publication 526: Charitable Contributions.
Also excluded are blood donations to the Red Cross or to blood banks and the income lost while volunteering for a qualified organization. However, you may be able to deduct documented, unreimbursed, out-of-pocket expenses that you paid in order to volunteer, like uniforms or transportation. Please see Publication 526 for specific examples of what expenses can and cannot be deducted.
Selected resources below may also help.
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